Ultra High-Field NMR Spectroscopy for Advanced Understanding of Materials

Description

UK graduates are invited to apply for a fully funded 42-month PhD studentship starting in October 2025 in the area of magic angle spinning (MAS) nuclear magnetic resonance (NMR) of solids. This opportunity will remain open until the position has been filled and so early applications are encouraged.

To extend the applicability of NMR, the two key limiting factors of sensitivity (the relative intensity of the NMR signals vs the noise level) and resolution (the smallest peak separation that can be measured) must be addressed. Both are significantly improved at higher external magnetic field and the recent advancements in magnet technology have enabled the development of commercial ultra high-field NMR system up to 28.2 T (1.2 GHz 1H frequency). This PhD project will explore the opportunities available in MAS NMR at ultra high-field NMR and develop new, advanced capabilities for high resolution NMR spectroscopy in solids, in particular for nuclei with spin larger than 1/2 (quadrupolar nuclei) and for disordered solids. The work builds on the strong dual NMR and materials science expertise and track record of the supervisor, enabling new tools for improved sensitivity/resolution.  

This studentship will allow a highly motivated candidate to participate in the development of ultra high-field MAS NMR for materials chemistry offering a unique research profile. The successful applicant will join an international and multidisciplinary research team that will provide complete student training, skills and development, ensuring strong employability. The project is based in the Department of Chemistry at the University of Liverpool, which is an international centre of excellence for the chemistry of advanced materials, with ample opportunities to work collaboratively. The successful applicant will have access to state-of-the-art local NMR facilities operating at up to 18.8 T (800 MHz 1H frequency), be able to perform experiments at world-leading large scale NMR research facilities including at the UK High-Field Solid-State NMR Facility (that operates NMR systems at 20 T (850 MHz 1H frequency), 23.5 T (1 GHz 1H frequency) and soon 28.2 T), and expand their research vision and interest by attending (inter)national conferences.

The successful candidate should have, or expect to have, at least a 2:1 Master degree or equivalent in Chemistry, Physics, Materials Science or closely related subject. The candidate should be highly motivated, curious, have competent English communication skills, computer skills and be able to work both as part of a team and independently. Project experience in NMR spectroscopy would be an advantage, but is not a prerequisite.

Applications should include (1) a cover letter containing (a) the applicant motivation in this PhD studentship and (b) a statement on teaching interests and commitment, (2) a full CV, and (3) the contact details of two academic referees and should be sent by email to Prof. Frédéric Blanc () indicating “Ultra high-field NMR PhD studentship 2024” in the subject line. 

Availability

Open to UK applicants

Funding information

Funded studentship

The funding for this position is from an EPSRC DTP studentship which details of eligibility are given on the EPSRC website. Only applications from candidates meeting these criteria will be considered.

Applications from non-UK/non-EU candidates will not be considered unless you have your own funding to cover the difference between UK/EU and non-UK/EU fees (around £22,000).

The award will pay full tuition fees and a stipend for 3.5 years. The stipend is of approximately £19,237 for 2024/2025 full time tax free per year for living costs and will rise each year with inflation.

Supervisors

References

For recent literature examples, see:
Cation Distribution and Oxide Ion Diffusion in La3Ga5-xGe1+xO14+0.5x Langasite Structure, L. Corti, I. Hung, A. Venkatesh, Z. Gan, J. B. Claridge, M. J. Rosseinsky, F. Blanc*, J. Am. Chem. Soc., 2024, 146(20), 14022-14035
Superionic Lithium Transport via Multiple Coordination Environments Defined by Two Anion Packing, G. Han, A. Vasylenko, L. M. Daniels, C. M. Collins, L. Corti, R; Chen, H. Niu, T. D. Manning, D. Antypov, M. S. Dyer, J. Lim, M. Zanella, M. Sonni, M. Bahri, H. Jo, Y. Dang, C. M. Robertson, F. Blanc, L. J. Hardwick, N. D. Browning, J. B. Claridge*, M. J. Rosseinsky*, Science, 2024, 383, 739-745.
Interfacial Bonding Between A Crystalline Metal-Organic Framework and An Inorganic Glass, C. Castillo-Blas, A. M. Chester, R. P. Cosquer, A. F. Sapnik, L. Corti, R. Sajzew, B. Poletto-Rodrigues, G. P. Robertson, D. J. M. Irving, L. N. McHugh, L. Wondraczek, F. Blanc*, D. A. Keen, T. D. Bennett*, J. Am. Chem. Soc., 2023, 145(42), 22913-22924.
Disorder and Oxide Ion Diffusion Mechanism in La1.54Sr0.46Ga3O7.27 from Nuclear Magnetic Resonance, L. Corti, D. Iuga, J. B. Claridge, M. J. Rosseinsky, F. Blanc*, J. Am. Chem. Soc., 2023, 21817
Towards Understanding of the Li Ion Migration Pathways in the Lithium Aluminium Sulphides Li3AlS3 and Li4.3AlS3.3Cl0.7 via 6,7Li Solid- State Nuclear Magnetic Resonance Spectroscopy, B. B. Duff, S. J. Elliott, J. Gamon, L. M. Daniels, M. J. Rosseinsky, F. Blanc, Chem. Mater., 2023, 27